Abstract: One of the keys to consolidating and expanding the poverty alleviation program’s achievements and making an effective connection with the rural revitalization project is to make the industrial poverty alleviation organically integrate with the villages. In the process of the industry to the countryside, large external enterprises not only need to cooperate with the government and the village, but also have to interact with small and medium-sized market entities in the poverty-stricken areas. They face the cooperation dilemma of how to integrate into the local market while avoiding damaging the interests of small and medium-sized enterprises. Unlike the state-centered and the social-centered approach, this paper takes the perspective of enterprises. This paper takes G Group’s industrial poverty alleviation project in LS County of the tea industry as a key case. It shows that through the embedding of organization, human resources, and production, the external enterprises can adapt the poverty alleviation industries to the local industry and social foundation. Meanwhile, by handling the external market link through differentiated embedding, the external enterprises can achieve the goal of “organic embedded” sustainable development.